ARISE Oh sleepy thread....
I had an opportunity to blow the cobwebs off the Z3 and prod a new bore-camera into the problem cylinder.
There is a problem, pictures to follow, it isnt pretty, post watershed material.
Update: worked out how to get the pictures off the camera!
Both exhaust valves have bits missing but this is the worst one, I havent mastered the Macro focus on the camera but this is enough evidence to form a plan.